• BPO颗粒

    BPO颗粒

 

Benzoyl Peroxide (BPO) Granules are a stabilized, granular form of benzoyl peroxide, widely utilized as a polymerization initiator and curing agent in various industrial applications. This form offers enhanced safety, ease of handling, and consistent performance compared to other forms like powders or pastes.

产品性能介绍

1. Chemical Identity

  • 化学名称: Benzoyl Peroxide

  • CAS编号: 94-36-0

  • Molecular Formula: C₁₄H₁₀O₄

  • Molecular Weight: 242.23 g/mol

  • Synonyms: Dibenzoyl Peroxide, BPO, Benzoic Peroxyanhydride


2. Physical and Chemical Properties

 

财产 价值观
外貌 White granular solid
Odor Faint odor of benzaldehyde
熔点 103–106 °C
密度 1.16 g/cm³ at 25 °C
Solubility in Water Insoluble
Solubility in Organic Solvents Soluble in acetone, benzene, chloroform; slightly soluble in ethanol
闪点

110 °C

Decomposition Temperature 131 °C (1-minute half-life)
Theoretical Active Oxygen Content 6.62%

3. Technical Data Sheet (TDS)

3.1. Product Specifications

 

范围 规格
Assay (BPO Content) 72–76%
Water Content 22–25%
Free Chloride ≤0.1%
Free Acid (as Benzoic Acid) ≤0.5%
外貌 White granular solid
堆积密度 500–600 kg/m³

3.2. Thermal Decomposition Data

 

Half-Life 温度
10 hours 73 °C
1 hour 92 °C
1 minute 131 °C

4. 应用

4.1. Polymer Industry

  • Initiator for Polymerization: BPO granules are extensively used to initiate the polymerization of monomers such as styrene, methyl methacrylate, and acrylates in the production of plastics, resins, and adhesives.

4.2. Composite Materials

  • Curing Agent: In unsaturated polyester and vinyl ester resins, BPO granules act as a curing agent, facilitating cross-linking during the fabrication of fiberglass-reinforced plastics.

4.3. Rubber Industry


5. Safety and Handling

5.1. Hazards Identification

  • Oxidizing Agent: BPO granules are strong oxidizers and can pose fire and explosion hazards, especially when dry or in contact with combustible materials.

  • Health Hazards: Exposure may cause skin and eye irritation. Inhalation of dust can irritate the respiratory tract.

5.2. Exposure Limits

  • NIOSH Recommended Exposure Limit (REL): TWA 5 mg/m³

  • OSHA Permissible Exposure Limit (PEL): TWA 5 mg/m³

  • Immediately Dangerous to Life or Health (IDLH): 1500 mg/m³

5.3. Personal Protective Equipment (PPE)

  • Eye Protection: Safety goggles or face shield

  • Skin Protection: Protective gloves and clothing

  • Respiratory Protection: Dust mask or respirator in case of inadequate ventilation

5.4. First Aid Measures

  • Inhalation: Move to fresh air. Seek medical attention if symptoms persist.

  • Skin Contact: Wash with soap and water. Remove contaminated clothing.

  • Eye Contact: Rinse cautiously with water for several minutes. Seek medical advice.

  • Ingestion: Do not induce vomiting. Seek immediate medical attention.


6. Storage and Stability

  • 储存条件: Store in a cool, dry, well-ventilated area away from heat sources and direct sunlight.

  • Temperature: Maintain storage temperature below 35 °C.

  • 包装: Typically available in 20 kg or 25 kg containers with inner polyethylene bags and outer fiber drums or cartons.

  • Stability: BPO granules are stable under recommended storage conditions but decompose upon heating, shock, or friction.


7. Regulatory Information

  • UN Number: 3104 (for BPO with ≥52% content)

  • Hazard Class: 5.2 (Organic Peroxides)

  • Packing Group: II

  • Regulatory Listings: BPO is listed under various regulatory frameworks, including REACH, TSCA, and OSHA.


8. Environmental Impact

  • Ecotoxicity: BPO is harmful to aquatic life with long-lasting effects.

  • Degradability: It decomposes into benzoic acid and oxygen, which can contribute to environmental oxygen demand.

BPO颗粒

应用场景

5.1. Polymer Industry Initiator for Polymerization: BPO is widely used to initiate the polymerization of monomers like styrene, methyl methacrylate, and acrylates in the production of plastics, resins, and adhesives. 5.2. Composite Materials Curing Agent: In unsaturated polyester and vinyl ester resins, BPO acts as a curing agent, facilitating cross-linking during the fabrication of fiberglass-reinforced plastics. 5.3. Pharmaceuticals and Cosmetics Acne Treatment: BPO is a common active ingredient in topical acne medications due to its antibacterial properties. 5.4. Food Industry Bleaching Agent: BPO is employed to bleach flour, whey, and cheese products, improving their appearance.

  • 品牌 :
    TF复合
  • 产品名称 :
    BPO颗粒
询问

常问问题

问:

BPO浆料在玻璃纤维行业中有什么用途?

答 :

过氧化苯甲酰(BPO)膏体主要用作不饱和聚酯和乙烯基酯树脂的固化引发剂。它有助于启动各种玻璃纤维制造方法中的聚合过程,例如手糊成型、喷涂成型、拉挤成型、浇铸成型和纤维缠绕成型。.

问:

为什么BPO(苯酚)以糊状而不是粉末状使用?

答 :

更安全(爆炸或火灾风险更低)、更易于操作和混合、粉尘更少、储存和运输过程中更稳定

问:

BPO糊剂可以单独用于固化吗?

答 :

不。BPO糊剂需要促进剂/加速剂(最常见的是辛酸钴)才能正确分解并产生自由基进行固化。.

问:

玻璃纤维生产中BPO浆料的典型用量是多少?

答 :

标准用量通常为树脂重量的 1.0% – 2.5%,具体取决于树脂类型、所需的固化速度和温度。.

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