Benzoyl Peroxide (BPO) is a white, crystalline powder known for its strong oxidizing properties. It serves as a free radical initiator in polymerization processes and is utilized across various industries, including plastics, pharmaceuticals, and cosmetics.
产品性能介绍
2. Chemical Identity
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化学名称: Benzoyl Peroxide
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CAS编号: 94-36-0
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Molecular Formula: C₁₄H₁₀O₄
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Molecular Weight: 242.23 g/mol
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Synonyms: Dibenzoyl Peroxide, BPO, Benzoic Peroxyanhydride
3. Physical and Chemical Properties
| 财产 | 价值观 |
|---|---|
| 外貌 | White crystalline powder |
| Odor | Odorless |
| Melting Point | 103–106 °C |
| Boiling Point | Decomposes before boiling |
| 密度 | 1.16 g/cm³ at 25 °C |
| Vapor Pressure | 0.009 Pa at 25 °C |
| Solubility in Water | Insoluble |
| Solubility in Organic Solvents | Soluble in acetone, benzene, chloroform; slightly soluble in ethanol |
| 闪点 | >110 °C |
| Decomposition Temperature | 133 °C (1-minute half-life) |
| Activation Energy | ~125.6 kJ/mol |
| Theoretical Active Oxygen Content | 6.62% |
4. Technical Data Sheet (TDS)
4.1. Product Specifications
| 范围 | 规格 |
|---|---|
| Assay (BPO Content) | 75.00–78.00% |
| Water Content | 21.00–25.00% |
| Free Chloride | ≤0.1% |
| Free Acid (as Benzoic Acid) | ≤0.5% |
| 外貌 | White granular powder |
| Bulk Density | 500–600 kg/m³ |
4.2. Thermal Decomposition Data
| Half-Life | Temperature |
|---|---|
| 10 hours | 72–73 °C |
| 1 hour | 92 °C |
| 1 minute | 131 °C |
5. 应用
5.1. Polymer Industry
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Initiator for Polymerization: BPO is widely used to initiate the polymerization of monomers like styrene, methyl methacrylate, and acrylates in the production of plastics, resins, and adhesives.
5.2. Composite Materials
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Curing Agent: In unsaturated polyester and vinyl ester resins, BPO acts as a curing agent, facilitating cross-linking during the fabrication of fiberglass-reinforced plastics.
5.3. Pharmaceuticals and Cosmetics
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Acne Treatment: BPO is a common active ingredient in topical acne medications due to its antibacterial properties.
5.4. Food Industry
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Bleaching Agent: BPO is employed to bleach flour, whey, and cheese products, improving their appearance.
6. Safety and Handling
6.1. Hazards Identification
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Oxidizing Agent: BPO is a strong oxidizer and can pose fire and explosion hazards, especially when dry or in contact with combustible materials.
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Health Hazards: Exposure may cause skin and eye irritation. Inhalation of dust can irritate the respiratory tract.
6.2. Exposure Limits
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NIOSH Recommended Exposure Limit (REL): TWA 5 mg/m³
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OSHA Permissible Exposure Limit (PEL): TWA 5 mg/m³
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Immediately Dangerous to Life or Health (IDLH): 1500 mg/m³
6.3. Personal Protective Equipment (PPE)
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Eye Protection: Safety goggles or face shield
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Skin Protection: Protective gloves and clothing
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Respiratory Protection: Dust mask or respirator in case of inadequate ventilation
6.4. First Aid Measures
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Inhalation: Move to fresh air. Seek medical attention if symptoms persist.
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Skin Contact: Wash with soap and water. Remove contaminated clothing.
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Eye Contact: Rinse cautiously with water for several minutes. Seek medical advice.
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Ingestion: Do not induce vomiting. Seek immediate medical attention.
7. Storage and Stability
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储存条件: Store in a cool, dry, well-ventilated area away from heat sources and direct sunlight.
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Temperature: Maintain storage temperature below 30 °C.
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包装: Typically available in 20 kg or 25 kg containers with inner polyethylene bags and outer fiber drums or cartons.
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Stability: BPO is stable under recommended storage conditions but decomposes upon heating, shock, or friction.
8. Regulatory Information
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UN Number: 3104 (for BPO with ≥52% content)
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Hazard Class: 5.2 (Organic Peroxides)
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Packing Group: II
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Regulatory Listings: BPO is listed under various regulatory frameworks, including REACH, TSCA, and OSHA.
9. Environmental Impact
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Ecotoxicity: BPO is harmful to aquatic life with long-lasting effects.
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Degradability: It decomposes into benzoic acid and oxygen, which can contribute to environmental oxygen demand.
10. Conclusion
Benzoyl Peroxide powder is a versatile chemical with applications spanning multiple industries. Its efficacy as a polymerization initiator and curing agent makes it invaluable in manufacturing processes. However, due to its reactive nature, strict adherence to safety guidelines is imperative to ensure safe handling and storage.
BPO粉末
系列 :
代理产品 >应用场景
Polymer Industry,Composite Materials,Pharmaceuticals and Cosmetics,Food Industry
品牌 :
TF复合
产品名称 :
BPO粉末
常问问题
问:
BPO浆料在玻璃纤维行业中有什么用途?
答 :
过氧化苯甲酰(BPO)膏体主要用作不饱和聚酯和乙烯基酯树脂的固化引发剂。它有助于启动各种玻璃纤维制造方法中的聚合过程,例如手糊成型、喷涂成型、拉挤成型、浇铸成型和纤维缠绕成型。.
问:
为什么BPO(苯酚)以糊状而不是粉末状使用?
答 :
更安全(爆炸或火灾风险更低)、更易于操作和混合、粉尘更少、储存和运输过程中更稳定
问:
BPO糊剂可以单独用于固化吗?
答 :
不。BPO糊剂需要促进剂/加速剂(最常见的是辛酸钴)才能正确分解并产生自由基进行固化。.
问:
玻璃纤维生产中BPO浆料的典型用量是多少?
答 :
标准用量通常为树脂重量的 1.0% – 2.5%,具体取决于树脂类型、所需的固化速度和温度。.
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