• Paraphthalic Unsaturated Polyester Resin (P-UPR)

    Paraphthalic Unsaturated Polyester Resin (P-UPR)

  • Paraphthalic Unsaturated Polyester Resin (P-UPR)

    Paraphthalic Unsaturated Polyester Resin (P-UPR)

 

Paraphthalic Unsaturated Polyester Resin, often abbreviated as P-UPR, is a high-performance resin engineered for superior chemical resistance, thermal stability, 和 mechanical strength. It is synthesized using terephthalic acid (commonly referred to as para-phthalic acid due to its molecular structure) as a key raw material. As a member of the aromatic polyester resin family, paraphthalic resin surpasses the performance of both orthophthalicisophthalic variants in several critical areas.

产品性能介绍

This document will explore the properties, advantages, applications, processing methods, and provide a comprehensive Technical Data Sheet (TDS). Designed to meet the demands of industries such as chemical processing, marine, 汽车, 和 infrastructure, paraphthalic resin is the material of choice when longevity and resistance to extreme environments are essential.


2. What is Paraphthalic Unsaturated Polyester Resin?

Paraphthalic UPR is a thermosetting resin derived from terephthalic acid 或者 dimethyl terephthalate (DMT), which is reacted with glycols such as propylene glycol 或者 neopentyl glycolmaleic anhydride. It contains unsaturated double bonds that allow cross-linking with monomers like styrene during curing, forming a three-dimensional network with high structural integrity.

What makes paraphthalic resin unique is its benzene ring structure in the para position, which confers rigidity and thermal resistance. This molecular arrangement makes P-UPR one of the most durable and stable resins available within the unsaturated polyester family.


3. Key Features and Benefits

Outstanding Chemical Resistance

Tolerates prolonged exposure to acids, alkalis, salts, and a variety of organic solvents.

Exceptional Mechanical Properties

High tensile, flexural, and impact strength ideal for structural and load-bearing applications.

Superior Thermal Stability

Heat resistance up to 160°C with special formulations.

Enhanced Weathering Resistance

Performs well under UV radiation, freeze-thaw cycles, and high humidity environments.

Long Service Life

Designed for applications demanding 20+ years of durability.

Excellent Compatibility with Reinforcements

Bonds exceptionally well with glass, aramid, and carbon fiber for high-strength composites.


4. Common Applications

Paraphthalic UPR is used across a wide range of industries that demand high-performance, corrosion-resistant composite materials.

 

Industry 应用场景
化学加工 FRP tanks, scrubbers, pipes, ducting, and containment systems
海洋 Hulls, decks, fishing boats, docks, and marine gratings
建造 Grating panels, cable trays, bridge decks, structural reinforcements
水处理 Wastewater tanks, flow channels, and covers
运输 Automotive bumpers, trailer panels, composite parts
Electrical Insulation panels, junction boxes, and cable carriers
基础设施 Road barriers, rail platforms, water management components

5. Processing Characteristics

Paraphthalic UPR is suitable for various fabrication processes. It is often supplied as a pre-promoted system but may also be modified to suit specific production techniques.

 

Processing Method Suitability
Hand Lay-up 出色的
Spray-up 出色的
Pultrusion Very Good (requires low viscosity)
Filament Winding Very Good
Vacuum Infusion Good with adjusted viscosity
Compression Molding Acceptable

Curing Agents:

Paraphthalic resins cure with MEKP, BPO, 或者 AIBN, often in conjunction with cobalt accelerators.

凝胶时间:

Adjustable between 8–25 minutes depending on application and catalyst system.


6. Technical Data Sheet (TDS)

Below is a representative TDS. The actual properties may vary depending on the manufacturer or the specific formulation.

📌 Liquid Resin Properties

 

财产 Typical Value 测试方法
Appearance Pale yellow to amber liquid Visual
Viscosity @ 25°C (mPa·s) 450 – 700 Brookfield, #3/60rpm
Acid Number (mg KOH/g) 12 – 22 ISO 2114
Solid Content (%) 62 – 68 ISO 3251
Styrene Content (%) 30 – 38 Gas Chromatography
Gel Time @ 25°C (1% MEKP) 10 – 18 minutes ISO 2535
Peak Exotherm Temperature (°C) 140 – 180 In-house method
Flash Point ~32°C ASTM D93
Shelf Life 6 months @ ≤ 25°C -

🔧 Cured Resin Mechanical Properties

 

财产 Typical Value 测试方法
Tensile Strength (MPa) 75 – 100 ISO 527
Tensile Modulus (GPa) 3.2 – 3.6 ISO 527
Elongation at Break (%) 2.5 – 4.0 ISO 527
Flexural Strength (MPa) 120 – 140 ISO 178
Flexural Modulus (GPa) 3.8 – 4.5 ISO 178
Izod Impact Strength (kJ/m²) 9 – 12 ISO 180
巴氏硬度 40 – 50 ASTM D2583

🌡️ Thermal and Chemical Resistance

 

财产 Typical Value 测试方法
Heat Distortion Temperature (°C) 110 – 130 ISO 75
Glass Transition Temperature (Tg) 120 – 135 DMA
Thermal Conductivity (W/m·K) ~0.2 ASTM C177
耐化学性 Excellent in acid/alkali ASTM C581
Water Absorption (24h) (%) < 0.25 ISO 62

7. Storage Guidelines

To maintain the shelf life and quality of paraphthalic resin:

  • Store in sealed containers between 15–25°C.

  • Avoid direct sunlight, moisture, 和 excess heat.

  • Use within 6 months of manufacture date.

  • Agitate before use to ensure uniformity.


8. Safety Precautions

  • Follow MSDS recommendations.

  • Keep away from open flamesheat sources.

  • Avoid inhalation of styrene fumes; use in ventilated areas.

  • Wear appropriate PPE—gloves, goggles, and a respirator if needed.

  • Dispose of unused material in accordance with local regulations.


9. Packaging Options

Paraphthalic UPR is supplied in:

 

Container Type Net Weight
Steel Drum 220–240 kg
IBC Tote 1000 kg
ISO Tank 20–24 MT

10. Summary and Conclusion

Paraphthalic Unsaturated Polyester Resin stands out as a top-tier resin system for advanced composite applications. Its performance benefits over traditional ortho- and isophthalic resins include:

  • Enhanced resistance to corrosive environments.

  • Long-term thermal and UV stability.

  • Structural reliability in demanding mechanical applications.

Paraphthalic Unsaturated Polyester Resin (P-UPR)

应用场景

涂料、粘合剂和复合材料

  • 产品名称 :
    o-phthalic resin
询问

常问问题

问:

What is the main difference between paraphthalic resin and isophthalic or orthophthalic resins?

答 :

The key difference lies in the acid component used during synthesis. Paraphthalic resin uses terephthalic acid, which has a para-configuration benzene ring structure. Isophthalic resin uses isophthalic acid (meta-configuration). Orthophthalic resin uses phthalic anhydride (ortho-configuration). This molecular difference gives P-UPR superior chemical resistance, thermal stability, and mechanical strength, making it more suitable for demanding industrial applications compared to isophthalic and orthophthalic resins.

问:

What industries benefit most from using paraphthalic unsaturated polyester resin?

答 :

P-UPR is particularly beneficial in: Chemical processing plants (tanks, ducts, scrubbers) Marine industry (boat hulls, docks, gratings) Infrastructure and construction (bridges, water treatment) Electrical and electronics (cable trays, enclosures) Its high durability and corrosion resistance make it ideal for harsh and corrosive environments.

问:

Can P-UPR be used with fiberglass reinforcements like chopped strand mat or woven roving?

答 :

Yes, absolutely. P-UPR is highly compatible with all standard reinforcements, including: Chopped strand mat (CSM) Woven roving Multiaxial fabrics Carbon fiber and aramid This compatibility results in excellent bonding, improving the structural strength and integrity of the final composite.

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